Sword and the Script: 10 leadership tips for 1:1 meetings with …

5 February, 2012 (08:34) | concise | By:

1. Be disciplined. ??The best thing that manager can provide to an employee is their undivided attention. ?Turn your phone off…whatever it is can wait 30 minutes.

2. Establish goals. ?Goals should include both their contributions to the organization and to their own professional development.

3. Seal it in ink. ?The sheer virtue of putting your discussions in writing, where both parties acknowledge the conversation with a signature, ensures a higher level of commitment. ?Things slip that are sealed in ink.

4. ?Measure goals. ?Peter Drucker is famous for the philosopy that, ?What gets measured, gets done.? Review the established goals quarterly for progress or completion. ?

5. ?Just say it. ?Don’t shy from a tough conversation. ?Managers cannot expect a change if they don’t clearly identify the issue. ?If there’s a problem or an issue, tell them clearly what the issue is and prescribe corrective action.

6. ?Remove obstacles. ?A key part of a manager?s job should be to remove obstacles so their employees can do their jobs. Junior managers ought to have the ability to solve their own problems with little intervention and when they seek a senior manager?s help, it?s because something is blocking them from doing their job — and by extension blocking you from doing yours.

7. Atta-boy or Atta-girl. ?The most underutilized tool in a manager’s toolkit is a compliment. ?If someone?s doing a great job ? tell them.

8. Say what not how. ?Tell an employee what you want done, not how to do it, unless they are seeking your help. ?Often employees will surprise you with ingenuity or creativity and as they grow they will gain confidence. ?This is an important part a manager?s responsibility to facilitate the growth of his or her employees.

9. Second chance at success. ?My father, who has long since passed, used to day, ?You?ve got to fall down 1,000 times before you?re an expert.? When an employee fails, gain something from that investment by asking them, “What did you learn?” ??

10. Performance and potential. ?This might ring of Jack Welch, because I first heard the term from a friend who was part of GE?s management program: ?pay for performance, promote for potential.

An earlier version of this post on 1:1 employee meetings was posted to Quora – and there are other submissions well worth reviewing. ?What tips would you add?

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Source: http://www.swordandthescript.com/2012/02/10-leadership-tips-for-11-meetings-with.html

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Holidays in New York Feel like Heaven | ArticleGoes – Free Dofollow …

4 February, 2012 (19:25) | concise | By:

Every summer season, New York City?s beaches are a favorite recreation destination. The Health Department provides the latest water quality information to ensure that your trip to the beach will be a safe and healthy one. Water quality conditions are analyzed on a regular basis and beaches are classified as either ?Open for Swimming,? ?Under Advisory,? or ?Closed ? Temporarily Restricted for Bathing.? If there are advisories due to wet weather conditions or increased pollution levels, they will be available here or by calling 311.

Five Awesome New York Beaches:
Rockaway Beach:

Yeah, yeah, yeah?I just told you I grew up here. But that does not mean Rockaway Beach is not great. Once considered the summer getaway destination for the rich and famous in the early 20th century, the Rockaway lost most of those wealthy visitors when they packed up and moved to the Hamptons to get even further away from Manhattan (and not so rich people) for a long weekend.

Long Beach:
At this not-too-crowded beach just a few blocks from the LIRR, boardwalk vendors rent out umbrellas ($12) and lounge chairs ($8 each), so you don?t have to lug them from home.

Orchard Beach:

The crescent-shaped beach is only 1.1 miles long and is entirely man-made, with minimal waves.

Robert Moses Beach

This Long Island state park is a little farther out, but it might be worth the extra travel time if Jones is too crowded for you?and if you have a car (the easiest way to get here). Be forewarned that the easternmost stretch, called Field 5 is clothing-optional.

Manhattan Beach

Manhattan Beach may seem like a bit of a paradox, considering that the sandy areas are bordered by a concrete promenade, but the atmosphere is calm and quiet: a more peaceful alternative to neighboring Coney Island.

A holiday to New York and the city of New York will be a special vacation for the entire family. The tours available are something everyone can enjoy. You need to take some time for your City Break New York to include a few of the museums and other historical sites. Between the tours and other attractions, you will find something new and exciting to do every day that you are in the exciting city of New York.

Steve is an articles writer whose major area of focus is travel. His articles on different travel topics like Holidays in New Yorkand New York Holiday are published on various online platforms. Don?t forget to visit his site at http://www.mynewyork.co.uk.

Source: http://articlegoes.com/holidays-in-new-york-feel-like-heaven.html

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Health: NursingJobBank.com

4 February, 2012 (06:09) | concise | By:

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Cleveland, OH – My Profile Account Manage your career through our interactive dashboard. My Jobs by Email Alerts Receive the latest matching jobs immediately to your inbox. Job Details Downtown law firm is expanding and seeks to add an experienced RN/Nurse Paralegals to their medical product liability litigation team. Responsibilities include reviewing medical charts and documentation; preparing medical chronologies and timeliness; reviewing, preparing and attending expert depositions; heavy client… contact; preparing matters for trial and attending to other case related matters. 3+ years of prior DEFENSE law firm/paralegal experience highly recommended but open to 5+ years of ICU, CCU, MedSurg or ER experience ONLY in addition to legal nurse degree AND 6+ months experience. Must be proficient in Word, excellent communicator and professional presentation. Full benefits include medical, dental, vision, 401(k), profit sharing, PTO, paid overtime, generous holiday time off and more. Candidate login

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CompHealth – North Carolina – Nurse Practitioner-General opening in , North Carolina. This and other nurse practitioner jobs brought to you by Nursing Job Cafe. Psychiatric clinic needs additional nurse practitioner support mid-December through February 2012. Will work on adult medical management in the clinic and also help with crisis and emergency cases. Clinic operates Monday through Friday 8 a.m. – 5 p.m. No call. DEA and North Carolina license required. Contract extensions are possible.100% Outpatient clinicMonday….Key Words: NP, Nurse, Practitioner, RN, Registered, Nurse, AND, BSN, NPC, CNP

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CompHealth – Minnesota – Nurse Practitioner-General opening in , Minnesota. This and other nurse practitioner jobs brought to you by Nursing Job Cafe. Southwestern Minnesota Clinic Group has an immediate need for a Psych trained NP. Psych certification preferred but not required. Will see patients of all ages in an outpatient clinic setting.Outpatient setting, all agesMon-Fri, 8am-5pm, will cover 2 clinicsPsych Certified preferred, must have experience with Psych PatientsWe offer comprehensive major medical and dental… insurance, life insurance, and a 401(k) retirement savings planWe offer competitive pay that may include incentives and bonusesYou are covered under our professional liability insuranceCompHealth has the best people to help you provide the best healthcare. Our experts in healthcare staffing deliver a rewarding experience that results in the best possible outcome for clients, healthcare providers and their patients.Key Words: NP, Nurse, Practitioner, RN, Registered, Nurse, AND, BSN, NPC, CNP

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Frisco, TX – Under general direction of the Business Unit Director, responsible for providing direction, guidance and management of the Lash Group Clinical Staff, assigned to the Call Center and in the Field. Works in collaboration with the Vice President, Director, Associate Director, Project Managers, Trainers and all other Lash Group team members as appropriate. Primary Duties and Responsibilities Functions in compliance with established clinical and operational policies and procedures. Serves as a consultant to customer for Program Development. Serves as point of contact for any issues or concerns that are escalated to the Manager’s level by clients, business partners, or consumers. Responsible for o …

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Home Healthcare Austin TX | Senior home care Austin Texas (TX …

3 February, 2012 (17:04) | concise | By:

[unable to retrieve full-text content]If the senior requires an injected medication or nursing care while improving from an operation, then home healthcareis needed. If the elderly family member needs help in bathing, cooking or housekeeping, then home care

Source: http://gotangels.com/616/home-healthcare-austin-tx/

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Indulge in Famous Filipino Food Recipes at Lutong Bahay | We all …

3 February, 2012 (16:00) | concise | By:


Indulge in Famous Filipino Food Recipes at Lutong Bahay

Any Filipino or non-Filipino, currently residing in the Philippines or in any other country in the world, can now indulge in famous Filipino food or ?pagkaing Pinoy? recipes right in the comfort of their own home. These Filipino food recipes are now available online at the lutong bahay website which is totally unrelated to lutong pinoy.com. All that one needs to visit the lutong bahay website is an internet connection. The recipes are provided for free along with the opportunity to forge new friendships and reconnect with old friends in the community of cooking enthusiasts.
The lutong bahay website can serve up virtually any dish considered among the Filipino lutong bahay foods. Pilipino cuisine is well represented, with everything from Pinoy breakfast recipes and viands or lutong ulam recipes to snacks or merienda recipes. The free recipes look very delectable with corresponding pictures from the Philippines.
Filipinos work hard in order to enjoy good cooking, plentiful food and hearty eating. Wherever they are, in the Philippines or abroad, Filipinos feast on food to mark special occasions. Friends from other countries and cultures are often invited to join such festivities. Various Filipino dishes from among the hundreds developed in Filipino or Pinoy cooking are served. Some of these Philippine or Pilipino foods recipes are very old, dating back to early Spanish times in the country. They are still well loved today although many other variations and spin offs have also been developed from them. New recipes are also being created by the young Filipino chefs.
Filipino cooking is spoken of as ?mga lutong Pinoy? and ?lutong Pilipino? by Filipinos while home cooked food is spoken of as ?mga lutong bahay? and ?lutuing bahay.? The collection of lutong bahay free recipes or lutong Pinoy free recipes available online from the Philippines can be perused to choose the best healthy and easy Filipino foods recipes. For those who want to try making traditional Filipino recipes but do not have the time or patience to cook everything from scratch, the Mama Sita recipes recommend the use of high quality ready mixes. Today, the use of the palayok or the native earthen pot is no longer required in cooking although they are still popular as serving vessels in restaurants or even in private parties.
A long term lutong Pinoy menu can be planned for even up to a year?s worth of regular meals and feasts. There are more than enough choices to be mixed and matched in regional cuisines, including Ilocano, Pampanga, Tagalog and Visayan foods, dishes and recipes, among others. Some of the local delights are the saluyot recipe of the Ilocos provinces; the Batangas bulalo recipe of Batangas province; the pancit chami recipe of Lucena, Quezon; and the pigar pigar recipe of Dagupan, Pangasinan. Some vegetable dishes are sinigang sa bayabas, sinigang sa miso and ginisang togue. There are also a lot of Filipino food recipes like the seafood kare kare recipe, the Spanish sardines recipe, the crab Maritess recipe, the sweet and sour lapu ? lapu recipe, the rellenong pusit recipe and the ginataang tilapia recipe.
The free Filipino recipes at lutong bahay also include store bought favorites like the Jollibee style spaghetti recipe, siopao sauce recipe, hopia recipe, sylvanas recipe and best ube chiffon cake recipe.
Articles are likewise offered, focusing on food and food related activities like the Lanzones Festival 2010 in the Philippines.

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Carnival Cruise Outline Enjoyable Ships

3 February, 2012 (13:40) | concise | By:

Carnival Cruise Outline Enjoyable ShipsTraveling means seeking representing fun and relaxation. With it can be top accomplish by riding a first-class cruise silhouette whose crucial services about bringing enjoyable to its customers. Cycle The Fun Ship with an atmosphere of all-day fun and party.

Carnival Cruise Ranks classify the word entertainment.Carnival Cruise Outline Enjoyable Ships They are built to cater enjoyment and excitement among younger passengers. Their pride is about creating memorable vacations for the guests and offering a open array of quality cruises that donate outstanding price in support of the money. This is the inland used for many entertainers and supplementary cruise ship jobs that can give all passengers the delight that they wanted.
Brief History

CCL has a large digit of cruise ships that travels to different parts of the world. The founder is Ted Arison, who started everything in 1972, with emphatically one send bought for only $1. Carnival was by its worst except Ted came up with a good idea of combining fun and travel. In 1989 its earliest acquisition was finished with the premium hand Holland America Line (this incorporated Windstar Cruises and Holland America Tours) and its subsequent in 1992, of the operator Seabourn Cruise Procession. Next this acquisition is the varying of the name beginning Carnival Cruise Line to Carnival Corporation. Dancing in the streets Corporation and P&O Princess Cruises plc. merged taking place 17 April 2003 creating one of the world?s biggest leisure travel companies: at the time P&O Princess Cruises was renamed Carnival plc.

Ships, Space, Destinations and Services

Carnival cruise twine is one of the world?s richest. Their specialty is to invent shorter and fewer dear ships.Carnival Cruise Outline Enjoyable Ships The ships are recognized in support of their Las Vegas-style decorations and entertainment. They are called ?The Fun Ships? observably because they bestow entertainment to passengers. In the midst of the open sort of activities by lodge, inhabitants will absolutely get hold of their stay meaningful. The cruise line is focused extra taking place entertainment services, in need to make all people?s travel comparable a carnival visit where audience came mainly for enjoyment. Festival ships are established owing to a direct with the colors of the American Flag. They?ve got a mascot named ?Fun Ship Freddy? a character in the shape of the ship?s distinctive funnel.

Since 1972, Carnival Cruise Procession has produced on the subject of 24 ships, with two further underneath construction. They have names with the word Dancing in the streets by it. Ships travel the length of the coasts of North and South America, Europe and further 60 countries all more than the world finding the bests destinations. Go starts on close-to-home ports originate resting on the cities of Florida.

If you are undecided where to get, you can select their tour called ?Cruise to Nowhere? A couple of days exploring the sea will achieve you witness the greatest of the world. Cruises to nowhere is a fantastic chance to taste the superb of services that includes delicious dining options, swish spas, exciting entertainment like the seaside theater and shopping friendly-casinos. There are no further cruise silhouette that will make you nowhere this fun and exciting.

Each day that you will come around up in a Carnival Cruise ship is another day of enjoyable. Revelry with above 3,500 people the length of with the crews and staffs.Carnival Cruise Outline Enjoyable Ships All in the send will achieve sure that you will go backside home-grown with a smile. Expression for a vacation packed with clear epoch and laughter. So get nearer and enjoy that Carnival difference by the The Enjoyable Send, come across a tour draped with amusement and joy. Provoke a cruise boat where enjoyment comes in waves.

Source: http://www.carlosprivateadventures.com/carnival-cruise-outline-enjoyable-ships/

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China announces $2.5B fund for small businesses (AP)

3 February, 2012 (03:45) | concise | By:

BEIJING ? China announced more help Wednesday for its struggling private business sector, unveiling a $2.5 billion fund to finance new small businesses and promising tax breaks and more lending for entrepreneurs.

The Cabinet announcement was one of the first concrete measures announced by the government following repeated pledges to help entrepreneurs who have been squeezed by a slump in U.S. and European demand and curbs on bank lending.

Entrepreneurs generate most of China’s new jobs and wealth, but thousands have been driven out of business. The survivors have slashed payrolls, raising concern among China’s communist leaders about possible unrest.

A Cabinet statement issued after a meeting led by Premier Wen Jiabao, the country’s top economic official, said small companies were essential to helping China keep growth fast and stable despite the global downturn.

The government will create a 15 billion yuan ($2.5 billion) fund “primarily to support the start-up of small and micro-enterprises,” it said.

It gave no details but also promised a cut in taxes and fees and said small businesses will be guaranteed a portion of government purchases of goods and services.

Beijing ordered the state-owned banking industry to lend freely to help China’s economy rebound from the 2008 global crisis. But it clamped down on credit to preventing overheating after annual economic growth soared above 10 percent in 2010.

Economic growth fell to a 2 1/2-year low of 8.9 percent in the final quarter of 2011.

Two surveys released Wednesday gave mixed signals on manufacturing activity in January but both showed it largely unchanged.

The state-affiliated China Federation of Logistics and Purchasing said its purchasing managers index rose 0.2 points to 50.5 from December’s 50.3 on a 100-point scale on which numbers above 50 indicate growth.

HSBC Corp. said its HSBC China Manufacturing PMI was little changed at 48.8 from December’s 48.7, suggesting a “moderate deterioration.”

The credit clampdown battered entrepreneurs as banks channeled their limited lending to politically favored government companies. Entrepreneurs turned to high-interest underground lenders. Thousands went bankrupt, leaving employees and suppliers unpaid.

The government responded in October by ordering banks to step up lending to small businesses, though it is unclear whether credit has increased.

Wednesday’s statement promised to create more small-scale financial institutions to serve entrepreneurs and rural companies.

___

Chinese Cabinet: http://www.gov.cn

Source: http://us.rd.yahoo.com/dailynews/rss/economy/*http%3A//news.yahoo.com/s/ap/20120201/ap_on_bi_ge/as_china_economy

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Dukan Diet Plan Achievement Secrets | IMSS Research Net

2 February, 2012 (14:37) | concise | By:

With unemployment levels therefore high, getting a winning resume can easily both find anyone for the best in the stack or even property anyone proper in the trash can. Creating your personal success along with mapping out your current future in your own terms can be empowering. The biggest issue most budding bloggers get can be coming up together with blogging posts.

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Your cover letter ought to ?wow? the reader. The much more anyone perform in it, the much better you will become. You can easily tell the reader the means you strive with regard to self improvement along with actively read success training manuals. Ultimately should you possess or even tend to be in a position for you to master these ten characteristics shared simply by effective entrepreneurs you will discover oneself to become one of them.

Source: http://imss-researchnet.org/dukan-diet-plan-achievement-secrets/

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Will Facebook deliver an IPO surprise?

2 February, 2012 (01:24) | concise | By:

FILE – In this May, 26, 2010 file photo, Facebook CEO Mark Zuckerberg talks about the social network site’s new privacy settings in Palo Alto, Calif. The Wall Street Journal reported Friday, Jan. 27, 2012 that Facebook is preparing to file initial paperwork for an offering that could raise as much as $10 billion and value the company at $75 billion to $100 billion (AP Photo/Marcio Jose Sanchez, File)

FILE – In this May, 26, 2010 file photo, Facebook CEO Mark Zuckerberg talks about the social network site’s new privacy settings in Palo Alto, Calif. The Wall Street Journal reported Friday, Jan. 27, 2012 that Facebook is preparing to file initial paperwork for an offering that could raise as much as $10 billion and value the company at $75 billion to $100 billion (AP Photo/Marcio Jose Sanchez, File)

(AP) ? Facebook, the social network that changed “friend” from a noun to a verb, is expected to file as early as Wednesday to sell stock on the open market. Its debut is likely to be the most talked-about initial public offering since Google in 2004.

The Menlo Park, Calif.-based company expects to raise as much as $10 billion, though some accounts say it could be less than that. At $10 billion, the company would be valued at $75 billion to $100 billion.

The highly anticipated documents Facebook files with the Securities and Exchange Commission will reveal how much it intends to raise from the stock market, what it plans to do with the money and details on the company’s financial performance and future growth prospects.

A stock usually starts trading three to four months after the filing.

Around the nation, regular investors and IPO watchers are anticipating some kind of twist ? perhaps a provision for the 800 million users of Facebook, a company that promotes itself as all about personal connections, to get in on the action.

After all, Facebook founder Mark Zuckerberg is anything but a conformist. He turns up at business conventions in a hoodie. “Cocky” is the word used to describe him most often, after “billionaire.” He was Time’s person of the year at 26. So when he takes Facebook public, why would he follow the Wall Street rules?

“Pandemonium is what I expect in terms of demand for this stock,” says Scott Sweet, senior managing partner at IPO Boutique, an advisory firm. “I don’t think Wall Street would want to anger Facebook users.”

The most successful young technology companies have a history of doing things differently. Google’s IPO prospectus contained a letter from its founders to investors that said the company believed in the motto “Don’t be evil.”

Facebook declined to comment, but Reena Aggarwal, a finance professor who has studied IPOs at Georgetown University’s McDonough School of Business, believes Zuckerberg will emulate Google’s philosophy, at least in principle.

Founders Larry Page and Sergey Brin wanted an IPO accessible to all investors, and said so in their first regulatory filing. Facebook may say something similar when it files to declare its intention to sell stock publicly.

Along with Wall Street investment banks, Google used a Dutch auction, named for a means of selling flowers in Holland, to sell its shares. It took private bids and allowed investors to say how many shares they wanted and what they were willing to pay.

The process wasn’t smooth, though, and Google had to slash its expected offer price at the last minute. If you bought at the IPO, for roughly $85 a share, you still did well: Google closed Tuesday at $580.

More recently, when it filed for an IPO last June, Groupon, which emails daily deals on products and services to its members, added a letter from its 30-year-old founder, Andrew Mason.

“We are unusual and we like it that way,” the letter said. “We want the time people spend with Groupon to be memorable. Life is too short to be a boring company.”

It’s almost become conventional for tech companies to include an unconventional letter when they make their stock market debut. It’s widely expected that Zuckerberg, in the very least measure of showmanship, will write one.

But IPO watchers wonder whether there might be a provision specifically designed to give the little-guy investor, even the casual Facebook user who doesn’t invest, a piece of the debut.

“There is a feeling that there will be something unique in store for Facebook users,” Aggarwal says.

When most companies go public, they let Wall Street investment banks handle everything, with the sweet ground-floor stock price reserved for big institutional investors.

But that probably won’t do for Facebook, created in a Harvard University dorm room eight years ago. Or Zuckerberg, whose antiestablishment credentials include spurning a $15 billion takeover offer from Microsoft.

Few expect Zuckerberg to offer a Dutch auction because of the Google experience. But he is at least as unorthodox as Google’s founders. People expect him to be in the driver’s seat on Wall Street, rather than hand over the controls to bankers.

Facebook is a vital part of people’s Internet lives and the most successful company in the history of social media. Its closest competitor, Google+, has less than a tenth the active membership ? 60 million people.

“While there is no such thing as untouchable, Facebook is getting near there, with even Google imitating it,” says Sweet, of IPO Boutique.

In “really hot IPOs,” 90 percent of the shares go to institutional investors and 10 percent to everyday investors, Sweet says. It’s a perk for the banks’ biggest clients, like Fidelity Investments or T. Rowe Price or hedge funds.

The funds pay big commissions to the banks for regularly trading large blocks of stocks or bonds. Those relationships are deep and long-lasting ? and lucrative for the banks. The funds expect to be rewarded.

But Morgan Stanley and Goldman Sachs, the banks expected to guide the Facebook IPO, are in an awkward place: They don’t want to tick off 800 million Facebook users ? but they don’t want to tick off Fidelity, either.

Most IPOs are underpriced, and the stock usually shoots up the first day. Lucky large investors get the basement price and usually a big payday if they sell on the first day. Smaller investors buy on the open market, after the price has spiked, and pay more.

And most early investors do sell. One university research paper found that about 70 percent of the new stock changes hands in the first two days. Groupon introduced 35 million shares, but on the first day its shares were traded almost 50 million times.

Ann Sherman, associate professor and IPO expert at DePaul University, raised the possibility that Facebook could set aside a portion of its shares for the small investor and use a lottery system if there is a lot of demand.

She says the U.S. is the only country without IPO rules that put traditional investors on an equal footing.

“Given that this is such a huge and popular IPO, I’ve been hoping that Facebook would use this opportunity to try a new method to bring in retail investors ? a public offer where shares are set aside for only individual investors,” Sherman says.

But Zuckerberg will also probably be careful how he plays his cards. He doesn’t want to anger Facebook users, but his primary goal is to raise money.

The recent experience of Groupon’s faltering IPO holds tough lessons for young entrepreneurs. After analysts started questioning its accounting, Groupon had to amend its regulatory filing several times.

Trying to salvage the IPO, founder Mason shed his trademark jeans and T-shirt and donned a suit. He dropped the irreverent talk and spoke about the company’s growth prospects at the IPO “roadshow” to impress investors.

Other companies have encountered problems when they went public and tried to reward customers. Upstart Internet phone company Vonage wanted to give customers a chance to buy up to 15 percent of its 31 million shares at its IPO at $17 apiece.

But when the shares fell 13 percent on the first day of trading, many of its small investors that had put in orders to buy didn’t want to pay the offer price. It gained the dubious title of one of the worst IPOs that year, something Facebook wants to avoid.

It’s also more expensive to sell shares to many people. When thousands of small investors want to buy in, it becomes a logistical nightmare to make sure each investor gets a prospectus with all the important information.

Banks like large investors because it costs about the same to process an order of 50 shares as 50,000. But William Hambrecht, founder and CEO of WR Hambrecht & Co., a firm that runs IPO auctions, says companies that value their customers benefit in the long run.

He gives the example of Boston Beer, maker of Samuel Adams, which went public in 1995. Its founder, James Koch, wanted to reward the people who made his company successful: the buyers of Sam Adams.

Koch set aside a quarter of his shares for the small investor. The deal was a big success and attracted more interest from his beer drinkers than there were shares available. Some people left out were dissatisfied.

Hambrecht says about two-thirds of the investors who bought those shares still owned the stock two years after the IPO. Even today, about a third still own it. Hambrecht says that’s because these investors appreciate the company’s product.

“Our argument has always been that true buyers of your stock ought to be your own customer base,” says Hambrecht. “As the great investor Peter Lynch said: Invest in what you know.”

Associated Press

Source: http://hosted2.ap.org/APDEFAULT/f70471f764144b2fab526d39972d37b3/Article_2012-02-01-Facebook%20IPO/id-bc33ea1196734292892dda6bb32348c7

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Oxygen molecule survives to enormously high pressures

1 February, 2012 (12:21) | concise | By:

ScienceDaily (Jan. 30, 2012) ? Using computer simulations, a RUB researcher has shown that the oxygen molecule (O2) is stable up to pressures of 1.9 terapascal, which is about nineteen million times higher than atmosphere pressure. Above that, it polymerizes, i.e. builds larger molecules or structures.

“This is very surprising” says Dr. Jian Sun from the Department of Theoretical Chemistry. “Other simple molecules like nitrogen or hydrogen do not survive such high pressures.” In cooperation with colleagues from University College London, the University of Cambridge, and the National Research Council of Canada, the researcher also reports that the behaviour of oxygen with increasing pressure is very complicated. It’s electrical conductivity first increases, then decreases, and finally increases again. The results are published in Physical Review Letters.

Weaker bonds, greater stability

The oxygen atoms in the O2 molecule are held together by a double covalent bond. Nitrogen (N2), on the other hand, possesses a triple bond. “You would think that the weaker double bond is easier to break than the triple bond and that oxygen would therefore polymerize at lower pressures than nitrogen” says Sun. “We found the opposite, which is astonishing at first sight.”

Coming together when pressure increases

However, in the condensed phase when pressure increases, the molecules become closer to each other. The research team suggests that, under these conditions, the electron lone pairs on different molecules repel one another strongly, thus hindering the molecules from approaching each other. Since oxygen has more lone pairs than nitrogen, the repulsive force between these molecules is stronger, which makes polymerization more difficult. However, the number of lone pairs cannot be the only determinant of the polymerization pressure. “We believe that it is a combination of the number of lone pairs and the strength of the bonds between the atoms,” says Sun.

The many structures of oxygen

At high pressures, gaseous molecules such as hydrogen, carbon monoxide, or nitrogen polymerize into chains, layers, or framework structures. At the same time they usually change from insulators to metals, i.e. they become more conductive with increasing pressure. The research team, however, showed that things are more complicated with oxygen. Under standard conditions, the molecule has insulating properties. If the pressure increases, oxygen metallises and becomes a superconductor. With further pressure increase, its structure changes into a polymer and it becomes semi-conducting. If the pressure rises even more, oxygen once more assumes metallic properties, meaning that the conductivity goes up again. The metallic polymer structure finally changes into a metallic layered structure.

Inside planets

“The polymerization of small molecules under high pressure has attracted much attention because it helps to understand the fundamental physics and chemistry of geological and planetary processes” explains Sun. “For instance, the pressure at the centre of Jupiter is estimated to be about seven terapascal. It was also found that polymerized molecules, like N2 and CO2, have intriguing properties, such as high energy densities and super-hardness.” Dr. Jian Sun joined the RUB-research group of Prof. Dr. Dominik Marx as a Humboldt Research Fellow in 2008 to work on vibrational spectroscopy of aqueous solutions. In parallel to this joint work in Solvation Science he developed independent research interests into high pressure chemical physics as an Early Career Researcher.

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The above story is reprinted from materials provided by Ruhr-Universitaet-Bochum, via AlphaGalileo.

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Journal Reference:

  1. Jian Sun, Miguel Martinez-Canales, Dennis Klug, Chris Pickard, Richard Needs. Persistence and Eventual Demise of Oxygen Molecules at Terapascal Pressures. Physical Review Letters, 2012; 108 (4) DOI: 10.1103/PhysRevLett.108.045503

Note: If no author is given, the source is cited instead.

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Source: http://feeds.sciencedaily.com/~r/sciencedaily/~3/UmpRdW3rov4/120130093911.htm

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